compds. Information. hazards. Marz, Michal; Kohout, Michal; Nevesely, Tomas; Chudoba, Josef; Prukala, Dorota; Nizinski, Stanislaw; Sikorski, Marek; Burdzinski, Gotard; Cibulka, Radek. A highly diastereoselective silver-catalysed cyclisation of a 2-substituted beta-allenic hydroxylamine is reported. Thus, we explored our method using chiral, nonracemic substrates (, Scheme 2. ChemInform Abstract: DMEAD: A New Dialkyl Azodicarboxylate for the Mitsunobu Reaction. RCH(CN)SO2Ph (R = Bu, 1-methylheptyl) with primary, e.g., MeCH:CHCH2OH, or secondary alcs. Reduction of nitro compounds by triethyl phosphite or triphenyl phosphine has been examined. datalyst and iodosobenzene diacetate is used as the stoichiometric oxidant. The basic objective of this review is to pay attention on the recent advances and applications of the Mitsunobu reaction particularly in last decade. The phosphorane Ph3P(OC6H3Cl-3,4)2 formed from PPh3, I, and 3,4-dichlorophenol was isolated as a highly reactive cryst. The Mitsunobu reaction is widely regarded as the pre-eminent method for performing nucleophilic substitutions of alcs. If you are not the author of this article and you wish to reproduce material from
"Reproduced from" can be substituted with "Adapted from".